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EC number: 201-070-7 | CAS number: 77-93-0
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Repeated dose toxicity: oral
Administrative data
- Endpoint:
- chronic toxicity: oral
- Remarks:
- combined repeated dose and carcinogenicity
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- other: Reliable scientific study, precedes establishment of guidelines and GLP
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 1 954
- Report date:
- 1954
Materials and methods
Test guideline
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- OECD Guideline 453 (Combined Chronic Toxicity / Carcinogenicity Studies)
- Deviations:
- yes
- Remarks:
- As this study precedes establishment of guideline, deviations would have occurred from the guideline later accepted.
- GLP compliance:
- no
- Remarks:
- precedes establishment of GLP
- Limit test:
- no
Test material
- Reference substance name:
- Triethyl citrate
- EC Number:
- 201-070-7
- EC Name:
- Triethyl citrate
- Cas Number:
- 77-93-0
- Molecular formula:
- C12H20O7
- IUPAC Name:
- triethyl citrate
- Test material form:
- liquid: viscous
Constituent 1
Test animals
- Species:
- rat
- Strain:
- Sprague-Dawley
- Sex:
- male/female
- Details on test animals or test system and environmental conditions:
- 4 per sex per dose group. Housed individually in wire mesh cages. Food and water was available ad libitum.
Administration / exposure
- Route of administration:
- oral: feed
- Vehicle:
- cotton seed oil
- Analytical verification of doses or concentrations:
- not specified
- Duration of treatment / exposure:
- lifetime
- Frequency of treatment:
- daily
Doses / concentrationsopen allclose all
- Remarks:
- Doses / Concentrations:
0.33% (equivalent to 30 mg/kg bw/d)
Basis:
nominal in diet
- Remarks:
- Doses / Concentrations:
1.0 % (equivalent to 200 mg/kg bw/d)
Basis:
nominal in diet
- Remarks:
- Doses / Concentrations:
3.0 % (equivalent to 600 mg/kg bw/d)
Basis:
nominal in diet
- No. of animals per sex per dose:
- 15
- Control animals:
- yes, plain diet
- Details on study design:
- Sprague-Dawley rats (15 males and 15 females/group) were provided with diet containing TEC at concentrations of 0, 0.33, 1.0 or 3.0% (estimated as 0, 165, 500 or 1500 mg/kg/day) in Rockland Rat Meal, 93.5-95% cottonseed oil, for two years. Weanling rats were maintained at the laboratory for one week before being placed on their respective control or treated diets. Animals were maintained throughout the study in individual suspended wire mesh cages, housed in air conditioned quarters, with food and water available ad libitum. Clinical observations were made daily (except Sunday) and individual body weights were measured weekly. Blood and urine evaluations were conducted at specified intervals. Scheduled interim sacrifices of animals included macroscopic examinations of thoracic and abdominal organs and microscopic examinations of the kidney and liver tissues. All animals that died spontaneously during the study, as well as all animals remaining at the termination of study (one or two years), were examined by a pathologist. At terminal sacrifice, microscopic examinations were made of kidney, liver, heart, lungs, spleen, stomach, small intestine, adrenals, ovaries, uterus, testes and seminal vesicles.
Results and discussion
Results of examinations
- Clinical signs:
- no effects observed
- Mortality:
- no mortality observed
- Body weight and weight changes:
- effects observed, treatment-related
- Description (incidence and severity):
- transiently decreased body weights
- Food consumption and compound intake (if feeding study):
- effects observed, treatment-related
- Description (incidence and severity):
- transient effects of decreased food intake associated with transiently decreased body weights.
- Food efficiency:
- not examined
- Water consumption and compound intake (if drinking water study):
- no effects observed
- Ophthalmological findings:
- not examined
- Haematological findings:
- no effects observed
- Clinical biochemistry findings:
- no effects observed
- Urinalysis findings:
- no effects observed
- Behaviour (functional findings):
- not examined
- Organ weight findings including organ / body weight ratios:
- no effects observed
- Gross pathological findings:
- no effects observed
- Histopathological findings: non-neoplastic:
- no effects observed
- Histopathological findings: neoplastic:
- no effects observed
- Details on results:
- Body weight data showed that males in the high-dose group had transiently lower weights, but there were no significant differences between the growth of TEC treated animals and control animals for the high-dose females or either sex in the low- and mid-dose groups. The effect in high-dose males may be attributable to their lower food consumption as compared to males in the other dose groups. There were no significant differences observed between treated and control groups for clinical evaluations or mortality. There were no significant differences between the groups for the following blood examinations: hemoglobin, erythrocyte count, nonprotein nitrogen and sugar determination. Urine tests for reaction, albumin, reducing substances and microscopic evaluation were all considered to be normal.
Terminal and interim autopsies disclosed no findings that were significant or attributable to TEC treatment. Size and weight of organs of the principal tissues at the time of autopsy were unremarkable. There were no significant differences between treated and control animals in comparison to the pathological findings.
Effect levels
- Dose descriptor:
- NOAEL
- Effect level:
- 600 mg/kg bw/day (nominal)
- Based on:
- test mat.
- Sex:
- male/female
- Basis for effect level:
- other: Initial doses were from 0.2 to 2.0 g/kg bw/d, as reviewed by JECFA. The 2.0 g/kg bw/d concentration was chosen by JECFA as the point of departure for risk assessment.
Target system / organ toxicity
- Critical effects observed:
- not specified
Applicant's summary and conclusion
- Conclusions:
- In a chronic (2-year) dietary oral toxicity study in rats with triethyl citrate, the NOAEL is 3% (estimated as 600 mg/kg/day), under the conditions of this study.
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