Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

Currently viewing:

Administrative data

First-aid measures

Description of first aid measures
Immediately remove contaminated clothing. If danger of loss of consciousness, place patient in recovery position and transport accordingly. Apply artificial respiration if necessary. First aid personnel should pay attention to their own safety.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.

On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.


Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11.


Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. Pulmonary odema prophylaxis. Medical monitoring for at least 24 hours.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide

Special hazards arising from the substance or mixture
toxic gases/vapours
The substances/groups of substances mentioned can be released in case of fire.

Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.

Accidental release measures

An explosive atmosphere can be formed in the case of a spillage. If large amounts are released contact the fire service.

Personal precautions, protective equipment and emergency procedures
Breathing protection required. Avoid contact with the skin, eyes and clothing.

Environmental precautions
Do not empty into drains.

Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr).
Cleaning operations should be carried out only while wearing breathing apparatus. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.

Handling and storage

Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Product should be worked up in closed equipment as far as possible. Handle in accordance with good industrial hygiene and safety practice. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.

Protection against fire and explosion:
Vapours may form explosive mixture with air. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.

Conditions for safe storage, including any incompatibilities
Segregate from acids and acid forming substances. Segregate from oxidants. Segregate from esters Segregate from lactones

Suitable materials for containers: Carbon steel (Iron), Stainless steel 1.4301 (V2), Stainless steel 1.4541, Stainless steel 1.4401, Stainless steel 1.4571, Low density polyethylene (LDPE), High density polyethylene (HDPE), glass
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.

Storage stability:
Storage duration: 24 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.

Transport information

Shippingopen allclose all
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (IMDG)

Remarksopen allclose all
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Control parameters

Components with occupational exposure limits


109-86-4: 2-methoxyethanol
110-91-8: morpholine

Exposure controls
Personal protective equipment
Respiratory protection:
Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)

Suitable respiratory protection for higher concentrations or long-term effect: Self-contained breathing apparatus.

Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
butyl rubber (butyl) - 0.7 mm coating thickness
fluoroelastomer (FKM) - 0.7 mm coating thickness
Polyethylene-Laminate (PE laminate) - ca. 0.1 mm coating thickness
Suitable materials for short-term contact (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374)
nitrile rubber (NBR) - 0.4 mm coating thickness
polyvinylchloride (PVC) - 0.7 mm coating thickness
chloroprene rubber (CR) - 0.5 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.

Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.

Body protection:
chemical-protection suit (f.e. according to EN 14605)

General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin, eyes and clothing. Avoid inhalation of vapour. When using, do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Store work clothing separately.

Stability and reactivity

Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.


Corrosion to metals:
Corrosive effects to metal are not anticipated.
Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.


Chemical stability
The product is stable if stored and handled as prescribed/indicated.

Possibility of hazardous reactions
Strong exothermic reaction with acids.


Conditions to avoid
Avoid all sources of ignition: heat, sparks, open flame.

Incompatible materials

Substances to avoid:
oxidizing agents, acids, nitrosating agents, Avoid contact with reactive components such as acids and organic components, for example ester and lactone., Avoid contact with monomers that can induce in alkaline medium polymerization.

Hazardous decomposition products

Hazardous decomposition products:
carbon monoxide, Carbon dioxide
toxic gases/vapours

Disposal considerations

Waste treatment methods

Incinerate in suitable incineration plant, observing local authority regulations.


Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.