Registration Dossier

Administrative data

First-aid measures

Immediately remove contaminated clothing.
If inhaled: Keep patient calm, remove to fresh air, seek medical attention.
On skin contact: Wash thoroughly with soap and water.
On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an
eye specialist.
On ingestion: Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling.
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

Suitable extinguishing media:
water spray, carbon dioxide, foam, dry powder
Unsuitable extinguishing media for safety reasons:
water jet
Special hazards arising from the substance or mixture: hydrogen chloride, carbon oxides
Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Do not breathe dust. Sources of ignition should be kept well clear. Avoid contact with the skin, eyes and clothing.
Personal protective equipment:
Respiratory protection: Suitable respiratory protection for lower concentrations or short-term effect: Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)
Hand protection: Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

Environmental precautions
Do not discharge into drains/surface waters/groundwater. Contain contaminated water/firefighting water.
Methods and material for containment and cleaning up
Take up mechanically and collect in suitable container (adequately labelled) for disposal. Collect waste in suitable containers, which can be labeled and sealed. Avoid raising dust.

Handling and storage

Handling:
Occupational hygiene: Avoid ingestion, inhalation, skin and eye contact. Handle in accordance with
good industrial hygiene practice and any legal requirements.
General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personalprotection equipment.
Storage:
Fire precautions
Storage facilities: Store in a cool, dry area with adequate ventilation
Segregation: No special precautions.
Storage conditions: Keep containers closed.
Sensitive to heat over 40 °C.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

Stability and reactivity

Disposal considerations