Registration Dossier

Administrative data

First-aid measures

4.1. Description of first aid measures
Immediately remove contaminated clothing. If danger of loss of consciousness, place patient in recovery position and transport accordingly. Apply artificial respiration if necessary. First aid personnel should pay attention to their own safety.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:
Immediately wash thoroughly with soap and water, seek medical attention.

On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.


4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further symptoms are possible


4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

5.1. Extinguishing media
Suitable extinguishing media:
water spray, dry powder, carbon dioxide

5.2. Special hazards arising from the substance or mixture
nitrogen oxides, carbon oxides
The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated.

5.3. Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Avoid contact with the skin, eyes and clothing. Avoid inhalation. Breathing protection required.

6.2. Environmental precautions
Do not empty into drains.

6.3. Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). Dispose of absorbed material in accordance with regulations.

6.4. Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

Handling and storage

7.1. Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Handle in accordance with good industrial hygiene and safety practice. Remove contaminated clothing and protective equipment before entering eating areas. Hands and/or face should be washed before breaks and at the end of the shift. When using do not eat, drink or smoke.

Protection against fire and explosion:
Take precautionary measures against static discharges. Keep away from sources of ignition - No smoking.

7.2. Conditions for safe storage, including any incompatibilities
Segregate from acids and bases.
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.

Storage stability:
Storage duration: 6 Months
May discolour after lengthy storage.
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.

7.3. Specific end use(s)
See exposure scenario(s) in the attachment to this safety data sheet.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

8.1. Control parameters

Components with occupational exposure limits

No occupational exposure limits known.

PNEC
freshwater: 0,0095 mg/l

marine water: 0,00095 mg/l

intermittent release: 0,095 mg/l

sediment (freshwater): 0,0352 mg/kg

sediment (marine water): 0,00352 mg/kg

soil: 0,00145 mg/kg

STP: 70,9 mg/l

oral (secondary poisoning):
No PNEC oral derived, as accumulation in organisms is not to be expected.


DNEL
worker:
Long-term exposure- systemic effects, dermal: 0,14 mg/kg

worker:
Long-term exposure- systemic effects, Inhalation: 0,5 mg/m3

consumer:
Long-term exposure- systemic effects, Inhalation: 0,125 mg/m3

consumer:
Long-term exposure- systemic effects, dermal: 0,08 mg/kg

consumer:
Long-term exposure- systemic effects, oral: 0,04 mg/kg


8.2. Exposure controls
Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Combination filter for gases/vapours of organic compounds and solid and liquid particles (f.e. EN 14387 Type A-P2)

Hand protection:
Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) etc.
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Eye protection:
Tightly fitting safety goggles (splash goggles) (e.g. EN 166)

General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes. Avoid inhalation of vapour. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Hands and/or face should be washed before breaks and at the end of the shift.

Stability and reactivity

10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.


Corrosion to metals:
No corrosive effect on metal.
Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.


10.2. Chemical stability
The product is stable if stored and handled as prescribed/indicated.

10.3. Possibility of hazardous reactions
Reacts with strong bases and heavy-metal salts. Reacts with strong acids. Strong exothermic reaction.


10.4. Conditions to avoid
Temperature: > 100 °C


10.5. Incompatible materials

Substances to avoid:
heavy metal salts, acids, bases, alkalies, oxidizing agents

10.6. Hazardous decomposition products

No hazardous decomposition products if stored and handled as prescribed/indicated.

Disposal considerations

13.1. Waste treatment methods

Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.


Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.