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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Inhalation

- Remove to fresh air.

- Oxygen or artificial respiration if needed.

Fire-fighting measures

- Extinguishing medium: In case of fire in close proximity, all means of extinguishing are  suitable.

- Hazards: Non-flammable.

- Container may explode if heated.

- Heating can release hazardous gases.

- Protective equipment: Self-contained breathing apparatus, full protective acid resistant suite.

- Unsuitable extinguishing medium: No restrictions

Special protective equipment for fire-fighters:

- Wear self-contained breathing apparatus and protective suit.

- Fire fighters must wear fire resistant personnel protective equipment.

- Wear chemical resistant oversuit

- Protect intervention team with a water spray as they approach the fire.

- Clean contaminated surface thoroughly

Other information

- Approach from upwind.

- Evacuate personnel to safe areas.

- Keep containers and surroundings cool with water spray.

- After the fire, proceed rapidly with cleaning of surfaces exposed to the fumes in order to limit equipment damage.

Accidental release measures

Personal precautions

- wear self-contained breathing apparatus in medium confinement/insufficient oxygen/in case of large uncontrolled emissions/in all circumstances    when the mask and cartridge do not give adequate protection.

- Use only respiratory protection that conforms to international/ national standards.

- In the case of vapour formation use a respirator with an approved filter.

- Approach from upwind.

- Suppress (knock down) gases/vapours/mists with a water spray jet.

- Avoid spraying the leak source.

- Try to re-position leaking containers, to have the leak in the gaseous phase.

- Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing.

- Prevent further leakage or spillage if safe to do so.

- Keep away from open flames, hot surfaces and sources of ignition.

- Keep away from incompatible products

- Avoid release into the environment

Methods for cleaning up

- Allow  to evaporate

- prevent product from entering drains

Handling and storage

Handling:

- Use in closed system

- Use only in well ventilated areas

- Use only equipment and materials which are compatible with the product.

- Prevent product vapours decomposition from electric arc action (welding).

- Prevent product vapours decomposition from contacting hot spots.

- Keep away from heat sources.

Storage requirement:

- Keep in a cool, well-ventilated place.

- Keep only in the original container at a temperature not exceeding 40 °C.

- Store in a receptacle equipped with a vent.

- Store in upright position only.

Packaging material: Steel drums

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
1080
Shipping information
Proper shipping name and description:
SULPHUR HEXAFLUORIDE
Language:
English
Labels:
2.2
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
1080
Shipping information
Proper shipping name and description:
SULPHUR HEXAFLUORIDE
Language:
English
Labels:
2.2
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
1080
Shipping information
Proper shipping name and description:
SULPHUR HEXAFLUORIDE
Labels:
non-flammable gas
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
1080
Shipping information
Proper shipping name and description:
SULPHUR HEXAFLUORIDE
Labels:
Non-flammable gas
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Occupational Exposure Limit:

8-h TWA TLV (ACGIH): 1,000 ppm. American Conference of Governmental Industrial Hygienists.

Stability and reactivity

Stability

- Stable under recommended storage conditions.

- Strong oxidizers, alkali metals and alkaline earth metals may cause fires or explosions.

- Vapours are heavier than air and may spread along floors.

- Hazardous Polymerisation/Polymerization: no

Conditions to avoid

- Heating

Materials to avoid

-  Oxidizing agents

Hazardous decomposition products

- Sulphur oxides, Sulphur compounds: Thionyl difluoride, Disulfur decafluoride

- Gaseous hydrogen fluoride (HF).

Disposal considerations

Waste from residues / unused products

- In accordance with local and national regulations.

- Refer to manufacturer/supplier for information on recovery/recycling.

Packaging treatment

- To avoid treatments, as far as possible, use dedicated containers.