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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Special instructions

Get medical advice/attention. Helpers should ensure their own protection.

Inhalation

IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If appropriate, give artificial respiration. Get medical advice/attention.

Skin contact

Remove/Take off immediately all contaminated clothing. IF ON SKIN: Gently wash with soap and water. Rinse continuously with water for several minutes. Get medical advice/attention.

Eye contact

IF IN EYES: Rinse continuously with water for several minutes. Get medical advice/attention.

Ingestion

Never give anything by mouth to an unconscious person. If swallowed, rinse mouth with water (only if the person is conscious) Get medical advice/attention.

Fire-fighting measures

Suitable extinguishing media

Water spray, Alcohol resistant foam, Foam, Carbon dioxide.

Special hazards arising from the substance or mixture

May emit toxic fumes of oxides of carbon and nitrogen during heating or fire.

Special protective equipment for fire-fighters

Isolating breathing apparatus eg. compressed breathing apparatus and protective clothing.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment as required. Avoid breathing dust/fume/gas/mist/vapours/spray. Provide sufficient ventilation. Isolate hazard area. Access of extra people to the spill area must be prevented.

Environmental precautions

Do not put into water system, drain or soil. Stop leak if there is no danger.

Methods and material for containment and cleaning up

Soak up with inert absorbent material (eg. vermiculite, sand) and dispose of as hazardous waste. Collect up into tightly sealable containers for disposal.

Handling and storage

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 18(4) for transported isolated intermediates. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at the manufacturing site.

If exposure is possible:

Precautions for safe handling

Handle in well-ventilated space. Handle under inert gas. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing.

Conditions for safe storage, including any incompatibilities

Store in a dry place. Store in a closed container. Store in a well ventilated place. Keep cool. Store at up-right position. Store at +2 - 8 °C. Store under inert gas.

Incompatible materials: Strong oxidants, Strong bases, Alcohols, Metal salts.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN 3082
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Chemical name:
diisopropyl azodicarboxylate
Language:
English
Labels:
9
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
UN 3082
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Chemical name:
diisopropyl azodicarboxylate
Language:
English
Labels:
9
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
UN 3082
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Chemical name:
diisopropyl azodicarboxylate
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
UN 3082
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Chemical name:
diisopropyl azodicarboxylate
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 18(4) for transported isolated intermediates. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at the manufacturing site.

If exposure is possible:

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety procedures. Wash hands thoroughly after handling.

Respiratory protection

Use respirator, filtration ABEK2-P3. In laboratories work in fume hood or under dust control hood.

Hand protection

Use protective gloves (e.g. nitrile or neopren gloves).

Eye protection

Use protective goggles.

Skin protection

Wear protective clothing.

Stability and reactivity

Reactivity

Not reactive under normal use and storage conditions.

Chemical stability

Stable under normal conditions.

Possibility of hazardous reactions

No dangerous reactions under normal use and storage conditions.

Conditions to avoid

Decomposes violently at or above 100 °C.

Incompatible materials

Strong oxidants, Strong bases, Alcohols, Metal salts.

Hazardous decomposition products

May emit toxic fumes of oxides of carbon and nitrogen during heating or fire.

Disposal considerations

Chemical incinerator equipped with an afterburner and scrubber is the recommended method of disposal for this material. Observe all local and national regulations when disposing of this material.