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EC number: 216-088-0 | CAS number: 1493-27-2
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Oxidising properties
Administrative data
- Endpoint:
- oxidising liquids
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- from 08 Jun 2015 to 08 Sept 2015
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Remarks:
- GLP compliant
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 015
- Report date:
- 2015
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- UN Manual of Tests and Criteria: Test O.2 (Test for oxidizing liquids)
- Deviations:
- yes
- Remarks:
- Deviation regarding the thickness of the aluminium bursting disk (see in "Any other information on materials and methods incl. tables")
- GLP compliance:
- yes (incl. QA statement)
- Remarks:
- Certificate from 2015-07-28
Test material
- Reference substance name:
- 1-fluoro-2-nitrobenzene
- EC Number:
- 216-088-0
- EC Name:
- 1-fluoro-2-nitrobenzene
- Cas Number:
- 1493-27-2
- Molecular formula:
- C6H4FNO2
- IUPAC Name:
- 1-fluoro-2-nitrobenzene
- Test material form:
- liquid
- Details on test material:
- Identity: 2-FLUORONITROBENZENE
CAS No.: 1493-27-2
Constituent 1
Results and discussion
Test results (Oxidising liquids)open allclose all
- Key result
- Sample tested:
- test mixture 1:1
- Parameter:
- mean pressure rise time
- Result:
- 10 975 ms
- Sample tested:
- reference mixture with 50% perchloric acid + cellulose (1:1 ratio)
- Parameter:
- mean pressure rise time
- Result:
- 85 ms
- Sample tested:
- reference mixture with 40% aqueous sodium chlorate + cellulose (1:1 ratio)
- Parameter:
- mean pressure rise time
- Result:
- 395 ms
- Sample tested:
- reference mixture with 65% nitric acid + cellulose (1:1 ratio)
- Parameter:
- mean pressure rise time
- Result:
- 2 955 ms
Any other information on results incl. tables
Preparation of the fibrous cellulose
Drying time: 1 day, 16 hours and 10 min
Drying temperature: Between 104.1°C and 105.3 °C (mean 104.9 °C)
Results for mixtures of reference items / cellulose
With a 50% perchloric acid aqueous solution as reference item
Assay No. |
Ref. item mass |
Cellulose mass |
Atmospheric pressure (kPa) |
Corrected pressure rise time (ms) |
Mean corrected pressure rise time (ms) |
Theoretical calculated min and max accepted value: ± 30% of the mean pressure rise time (ms) |
1 |
2.5 |
2.5 |
98.1 |
90 |
85 |
|
2 |
2.5 |
2.5 |
98.1 |
75 |
|
|
3 |
2.5 |
2.5 |
98.1 |
91 |
[59 ; 111] |
|
4 |
2.5 |
2.5 |
98.1 |
71 |
|
|
5 |
2.5 |
2.5 |
98.1 |
100 |
|
With a 40% sodium chlorate aqueous solution as reference item
Assay No. |
Ref. item mass (g) |
Cellulose mass |
Atmospheric pressure (kPa) |
Corrected pressure rise time (ms) |
Mean corrected pressure rise time (ms) |
Theoretical calculated min and max accepted value: ± 30% of the mean pressure rise time (ms) |
2 |
2.5 |
2.5 |
98.1 |
426 |
395 |
|
3 |
2.5 |
2.5 |
98.1 |
363 |
|
|
4 |
2.5 |
2.5 |
98.1 |
446 |
[276 ; 514] |
|
5 |
2.5 |
2.5 |
98.2 |
413 |
|
|
6 |
2.5 |
2.5 |
98.2 |
325 |
|
Remark: Another assay (No. 1) was performed but it was not taken into account as it did not comply with the quality criteria.
With a 65% nitric acid aqueous solution as reference item
Assay No. |
Ref. item mass (g) |
Cellulose mass |
Atmospheric pressure (kPa) |
Corrected pressure rise time (ms) |
Mean corrected pressure rise time (ms) |
Theoretical calculated min and max accepted value: ± 30% of the mean pressure rise time (ms) |
1 |
2.5 |
2.5 |
98.2 |
3372 |
2955 |
|
2 |
2.5 |
2.5 |
98.2 |
2716 |
|
|
3 |
2.5 |
2.5 |
98.2 |
2649 |
[2068 ; 3842] |
|
4 |
2.5 |
2.5 |
98.2 |
2756 |
|
|
5 |
2.5 |
2.5 |
98.2 |
3284 |
|
Results with mixtures of test item / cellulose
Assay No. |
Test item mass (g) |
Cellulose mass |
Atmospheric pressure (kPa) |
Corrected pressure rise time (ms) |
Mean corrected pressure rise time (ms) |
Theoretical calculated min and max accepted value: ± 30% of the mean pressure rise time (ms) |
1 |
2.5 |
2.5 |
98.2 |
12557 |
10975 |
|
4 |
2.5 |
2.5 |
98.2 |
10675 |
|
|
6 |
2.5 |
2.5 |
98.2 |
8601 |
[7682 ; 14268] |
|
7 |
2.5 |
2.5 |
98.2 |
12761 |
|
|
8 |
2.5 |
2.5 |
98.1 |
10283 |
|
Remark: The pressure did not rise Patm+ 2070 kPa for the assays No. 2 and 5 due to leaks. The assay No. 3 was performed but it was not taken into account as the result was not recorded.
Conclusion
The mean pressure rise times obtained with the three reference items / cellulose mixtures and with the test item / cellulose mixture were:
Mean pressure rise time (ms) |
||
Reference items |
Test item |
|
50% perchloric acid solution |
85 |
10975 |
40% aqueous sodium chlorate solution |
395 |
|
65% aqueous nitric acid solution |
2955 |
Applicant's summary and conclusion
- Interpretation of results:
- GHS criteria not met
- Conclusions:
- The mean pressure rise time obtained with the test item / cellulose mixture was higher than the mean pressure rise times obtained with the three mixtures of reference item / cellulose. The test item is thus not assigned to Division 5.1 and not classified as an oxidising liquid under CLP Regulation.
- Executive summary:
2-Fluoronitrobenzene was tested for its oxidizing properties in compliance with United Nations Recommendations on the Transport of Dangerous Goods - Manual of Tests and Criteria - Fifth revised edition (2009) - Method O.2 (Part III, Section 34.4.2) and under GLP conditions. The mean pressure rise time obtained with the test item / cellulose mixture was compared to the mean pressure rise times obtained with the three mixtures of reference items / cellulose and demonstrated to be higher:
Mean pressure rise time (ms)
Reference items
Test item
50% perchloric acid solution
85
10975
40% aqueous sodium chlorate solution
395
65% aqueous nitric acid solution
2955
The test item was thus not assigned to Division 5.1 and not classified as an oxidising liquid under CLP Regulation.
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