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Guidance on Safe Use

First-aid measures

General information:

Symptoms of poisoning may even occur after several hours; therefore, medical observation for at least 48 hours after the accident

Eye contact

Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.

Inhalation

Supply fresh air; consult doctor in case of complaints.

Skin contact

Generally, the product does not irritate the skin.

Ingestion

Get medical attention immediately. Call a poison center or physician.

Fire-fighting measures

Extinguishing media

Use fire extinguishing methods suitable to surrounding conditions.

Special hazards arising from the substance

Hazards from the substance: Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.

Hazardous combustion products: Decomposition products may include the following materials: Carbon dioxide, carbon monoxide

Advice for firefighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.

Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Use respiratory protective device against the effects of fumes/dust/aerosol. Wear protective clothing. Wear protective equipment. Keep unprotected persons away. Keep away from ignition sources and ensure adequate ventilation.

For non-emergency personnel: No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.

For emergency responders: If specialised clothing is required to deal with the spillage, take note of any information for suitable and unsuitable materials. See also the information in "For non-emergency personnel".

Environmental precautions: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up

Small spill: Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.

Large spill: Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.

Contaminated absorbent material may pose the same hazard as the spilt product.

Handling and storage

Precautions for safe handling

Protective measures: Put on appropriate personal protective equipment. Do not ingest. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source.

Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container.

Advice on general occupational hygiene

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.

Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials and food and drink.

Eliminate all ignition sources.

Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. Freezing will affect physical condition but will not damage. Thaw and mix before using.

Transport information

Land transport (UN RTDG/ADR/RID)

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Void

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Inland waterway transport (UN RTDG/ADN(R))

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Marine transport (UN RTDG/IMDG)

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Air transport (UN RTDG/ICAO/IATA)

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Exposure controls / personal protection

Recommended monitoring procedures:

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.

Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination of hazardous substances.

Exposure controls

Appropriate engineering controls: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapour or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.

Individual protection measures

Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.

Eye/face protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is

necessary to avoid exposure to liquid splashes, mists, gases or dusts.

Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling Chemical products if a risk assessment indicates this is necessary.

Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Other skin protection: Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.

Respiratory protection: Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Environmental exposure controls: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Stability and reactivity

Chemical Stability: Stable under normal conditions and pressures.

Conditions to Avoid: Avoid all possible sources of ignition (spark or flame). Do not pressurise, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatibility: Hydrolyzes in water to form alcohol and titanium dioxide. Reactive or incompatible with the following materials: Oxidizing material.

Hazardous Decomposition: Irritating and toxic fumes and gases.

Hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.

Disposal considerations

Waste should only be disposed of via a licensed waste contractor. The European Waste Catalogue (EWC) and European Waste List

(EWL) is a harmonized list of wastes. Waste materials should be classified prior to final disposal with EWC-codes. Wastes and empty containers should be treated based on their classification and properties referring to local and national waste management regulations. Waste management options: Dispose of to non-hazardous or hazardous waste landfill (Council Directive on the landfill of waste 99/31/EU and Council Decision establishing criteria and procedures for the acceptance of waste at landfills 2003/33/EU) or dispose of via hazardous waste incineration.

The generation of waste should be avoided or minimized wherever possible. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste legislation and any local waste management regulations.

Waste codes should be assigned by the user, preferably in discussion with the waste disposal authorities. All wastes containing residues of the substance or its hazardous degradation products shall be classified as hazardous waste.

All wastes containing residues of the substance or its hazardous degradation products should be disposed of as hazardous waste to authorized hazardous waste incineration plants, operated according to Directive 2008/98/EC on waste, Directive 2000/76/EC on the incineration of waste and Best Available Techniques for Waste Incineration as described in the respective BREF of August 2006.

Contaminated packaging: Contaminated packaging should be emptied as far as possible and disposed of as hazardous waste to

incineration plants in accordance with Directive 2000/76/EC. Clean packaging material should be subjected to waste management schemes (recovery, recycling, re-use) according to local waste management regulations.

The substance and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.