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Diss Factsheets

Administrative data

Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
12-18 Jan 2011
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Guideline study (EU A.4; OECD 104)

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2011
Report date:
2011

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
GLP compliance:
yes (incl. QA statement)
Type of method:
effusion method: vapour pressure balance

Test material

Constituent 1
Reference substance name:
Montan waxes, type KPS
IUPAC Name:
Montan waxes, type KPS
Details on test material:
Test item: Licowax KPS FL
Storage conditions: room temperature

Results and discussion

Vapour pressure
Temp.:
25 °C
Vapour pressure:
0 Pa

Any other information on results incl. tables

The vapour pressure was measured in the temperature range of 22 °C to 124 °C. Above 73 °C a vapour pressure could be measured. The measured vapour pressures at the corresponding temperatures are listed in the following table:

Temperature/°C     Vapour pressure/hPa

72.6                          1.9 x 10-5

76.6                          2.7 x 10-5

79.4                          3.2 x 10-5

82.7                          4.3 x 10-5

89.7                          1.0 x 10-4

94.3                          1.3 x 10-4

98.7                          1.7 x 10-4

103.0                       2.3 x 10-4

106.5                       2.8 x 10-4

112.4                       4.2 x 10-4

118.9                      8.2 x 10-4

123.6                      1.2 x 10-3

The values for 20, 25 and 50 °C are calculated from the measurement curve, using the Antoine constants A, B and C.

T/°C       p/hPa           log(p/hPa)=A+B/(C+T[°C])

20          6.39E-08                              A=9.01057

25          1.19E-07                              B=-4750.52

50          2.04E-06                              C=273.15

 Final Results

Vapour Pressure

The calculated vapour pressure values are extrapolated

T/°C  p/hPa          p/Pa

20     6.4x10-8        6.4x10-6

25     1.2x10-7        1.2x10-5

50     2.0x10-6        2.0x10-4

Applicant's summary and conclusion

Conclusions:
The vapour pressure of the test substance is 0.000012 Pa at 25 °C.
Executive summary:

The vapour pressure of the test substance was determined in a guideline study (EU A.4; OECD TG 104) with a vapour pressure balance (effusion method). The vapour pressure is 0.000012 Pa at 25 °C.