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Classification & Labelling & PBT assessment

GHS

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General Information

Implementation:
EU
Type of classification:
self-classification
Remarks:

This C&L information includes all of the harmonized classification information provided for this substance in Annex VI in the EU Regulation 1272/2008 (CLP):

Harmonized Classification and labelling as depicted in Annex VI in EU regulation 1272/2008 (CLP):

Index-Nr.: 612 -001 -01 -6; mono-methylamine … %

Flam. Liq. 1, H224

Acute Tox. 4 *, H302

Acute Tox 4, H332

Skin Corr. 1B, H314

SCL: STOT SE 3; H335: C ≥ 5 %

Registrant specific C&L exceeding the harmonised C&L above:

Furthermore, additional self-classifications / -labellings are included (Acute Tox. 3, H331; Eye Damage 1, H318; EUHG9071).

Related composition

Related composition:
Monomethylamine
Monomethylamine

Classificationopen allclose all

Explosives
Reason for no classification:
data conclusive but not sufficient for classification
Flammable gases and chemically unstable gases
Reason for no classification:
hazard class not applicable
Aerosols
Reason for no classification:
data conclusive but not sufficient for classification
Reason for no classification:
hazard class not applicable
Oxidising gases
Reason for no classification:
hazard class not applicable
Gases under pressure
Reason for no classification:
hazard class not applicable
Flammable liquids
Hazard category:
Flam. Liquid 1
Hazard statement:
H224: Extremely flammable liquid and vapour.
Flammable solids
Reason for no classification:
hazard class not applicable
Self-reactive substances and mixtures
Reason for no classification:
data conclusive but not sufficient for classification
Pyrophoric liquids
Reason for no classification:
data conclusive but not sufficient for classification
Pyrophoric solids
Reason for no classification:
hazard class not applicable
Self-heating substances and mixtures
Reason for no classification:
data conclusive but not sufficient for classification
Substances and mixtures which in contact with water emit flammable gases
Reason for no classification:
data conclusive but not sufficient for classification
Oxidising liquids
Reason for no classification:
data conclusive but not sufficient for classification
Oxidising solids
Reason for no classification:
hazard class not applicable
Organic peroxides
Reason for no classification:
data conclusive but not sufficient for classification
Corrosive to metals
Reason for no classification:
data lacking
Desensitized explosives
Reason for no classification:
data lacking
Acute toxicity - oral
Hazard category:
Acute Tox. 4
Hazard statement:
H302: Harmful if swallowed.
Acute toxicity - dermal
Reason for no classification:
data conclusive but not sufficient for classification
Acute toxicity - inhalation
Hazard category:
Acute Tox. 3
Hazard statement:
H331: Toxic if inhaled.
Skin corrosion / irritation
Hazard category:
Skin Corr. 1B
Hazard statement:
H314: Causes severe skin burns and eye damage.
Serious eye damage / eye irritation
Hazard category:
Eye Damage 1
Hazard statement:
H318: Causes serious eye damage.
Respiratory sensitisation
Reason for no classification:
data conclusive but not sufficient for classification
Skin sensitisation
Reason for no classification:
data conclusive but not sufficient for classification
Aspiration hazard
Reason for no classification:
data conclusive but not sufficient for classification
Reproductive toxicity
Reason for no classification:
data conclusive but not sufficient for classification
Effects on or via lactation
Reason for no classification:
data conclusive but not sufficient for classification
Germ cell mutagenicity
Reason for no classification:
data conclusive but not sufficient for classification
Carcinogenicity
Reason for no classification:
data conclusive but not sufficient for classification
1. Specific target organ toxicity - single (STOT-SE)
Hazard category:
STOT Single Exp. 3
Hazard statement:
H335: May cause respiratory irritation.
Affected organs:
other: Respiratory system, stomach, intestines
Route of exposure:
inhalation
1. Specific target organ toxicity - repeated (STOT-RE)
Reason for no classification:
data conclusive but not sufficient for classification
1.
Concentration range (%):
>= 5
Hazard categories:
STOT Single Exp. 3
Hazardous to the aquatic environment (acute / short-term)
Reason for no classification:
data conclusive but not sufficient for classification
Hazardous to the aquatic environment (long-term)
Reason for no classification:
data conclusive but not sufficient for classification
Hazardous to the ozone layer
Reason for no classification:
data conclusive but not sufficient for classification
Additional hazard classes:
For STOT SE 3 (C>=5%): H335: May cause respiratory irritation.

Labelling

Signal word:
Danger

Hazard pictogram

GHS02: flame
GHS05: corrosion
GHS06: skull and crossbones

Hazard statements

H224: Extremely flammable liquid and vapour.
H302: Harmful if swallowed.
H331: Toxic if inhaled.
H314: Causes severe skin burns and eye damage.
H335: May cause respiratory irritation.

Precautionary statements

P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P241: Use explosion-proof [electrical/ventilating/lighting/...] equipment.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER/doctor/…
P405: Store locked up.
P501: Dispose of contents/container to ...

Additional labelling requirements

EUH071: Corrosive to the respiratory tract.
The data for MMA indicate that the mechanism of inhalation toxicity is corrosivity, as such this additional labelling shall also be applied.

Notes