Registration Dossier

Administrative data

First-aid measures

4.1. Description of first aid measures
Remove contaminated clothing. If danger of loss of consciousness, place patient in recovery position and transport accordingly. Apply artificial respiration if necessary.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:
Wash thoroughly with soap and water.

On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.


4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further symptoms are possible


4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

5.1. Extinguishing media
Suitable extinguishing media:
water spray, dry powder, carbon dioxide

5.2. Special hazards arising from the substance or mixture
nitrogen oxides, carbon oxides
The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated. Cool endangered containers with water-spray.

5.3. Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. If exposed to fire, keep containers cool by spraying with water.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation. Avoid all sources of ignition: heat, sparks, open flame. Avoid contact with the skin, eyes and clothing. Do not breathe vapour/aerosol/spray mists.

6.2. Environmental precautions
Do not empty into drains.

6.3. Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations.

6.4. Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

Handling and storage

7.1. Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Handle in accordance with good industrial hygiene and safety practice.

Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.

7.2. Conditions for safe storage, including any incompatibilities
Segregate from acids and bases.
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.

Storage stability:
Storage duration: 24 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.

Protect from temperatures above: 80 °C

7.3. Specific end use(s)
See exposure scenario(s) in the attachment to this safety data sheet.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

8.1. Control parameters

Components with occupational exposure limits


115-19-5: 2-Methylbut-3-yn-2-ol
OEL 3 mg/m3 ; 0,9 ppm (TRGS 900 (DE))
Ceiling limit value/factor: 2
Short Term Exposure Classification: (TRGS 900 (DE))
Category I: Substances for which the localized effect has an assigned exposure limit or for substances with a sensitizing effect in respiratory passages

PNEC
freshwater: 0,5 mg/l

marine water: 0,0359 mg/l

intermittent release: 5 mg/l

sediment (freshwater): 1,13 mg/kg

sediment (marine water): 0,144 mg/kg

soil: 0,108 mg/kg

STP: 10 mg/l


DNEL
worker:
Short-term exposure - local effects, Inhalation: 6 mg/m3

worker:
Long-term exposure- systemic effects, dermal: 0,3 mg/kg

worker:
Long-term exposure- systemic effects, Inhalation: 1,18 mg/m3

worker:
Long-term exposure - local effects, Inhalation: 3 mg/m3

consumer:
Long-term exposure- systemic effects, dermal: 0,2 mg/kg

consumer:
Long-term exposure- systemic effects, Inhalation: 0,3 mg/m3

consumer:
Long-term exposure- systemic effects, oral: 0,1 mg/kg

consumer:
Long-term exposure - local effects, Inhalation: 0,4 mg/m3


8.2. Exposure controls
Personal protective equipment
Respiratory protection:
Consider the risk management measures as outlined in the exposure scenario.

Hand protection:
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
butyl rubber (butyl) - 0.7 mm coating thickness
fluoroelastomer (FKM) - 0.7 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Consider the risk management measures as outlined in the exposure scenario.

Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield., Consider the risk management measures as outlined in the exposure scenario.

General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin, eyes and clothing. Do not inhale gases/vapours/aerosols. Wearing of closed work clothing is required additionally to the stated personal protection equipment.

Stability and reactivity

10.1. Reactivity

Corrosion to metals:
No corrosive effect on metal.
Reactions with water/air: Reaction with: water
Flammable gases: no


10.2. Chemical stability
The product is stable if stored and handled as prescribed/indicated.

10.3. Possibility of hazardous reactions
Strong exothermic reaction with acids. Reacts with bases. The progress of reaction is exothermic.


10.4. Conditions to avoid
Avoid heat.

10.5. Incompatible materials

Substances to avoid:
bases, strong acids

10.6. Hazardous decomposition products

Hazardous decomposition products:
acetone; propan-2-one; propanone, acetylene (ethyne)

Disposal considerations

13.1. Waste treatment methods

Incinerate in suitable incineration plant, observing local authority regulations.

A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.


Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.