Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

General advice : Take off contaminated clothing and shoes immediately.
Inhalation : Remove to fresh air.
If symptoms persist, call a physician.
Skin contact : Wash off immediately with soap and plenty of water.
If symptoms persist, call a physician.
Eye contact : Rinse immediately with plenty of water, also under the eyelids.
If eye irritation persists, consult a specialist.
Ingestion : Clean mouth with water and drink afterwards plenty of water.
Do NOT induce vomiting.
Consult a physician.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media: CO2, foam or dry powder

Special hazards arising from the substance or mixture
Specific hazards during fire fighting: In the event of fire be aware of formation of noxious fumes.

Advice for firefighters
Special protective equipment for fire-fighters: Firemen must wear self-contained breathing apparatus.
Further information : Do not allow run-off from fire fighting to enter drains or water courses.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Personal precautions : Use personal protective equipment.

Environmental precautions
Environmental precautions : Do not flush into surface water or sanitary sewer system.
Avoid subsoil penetration.

Methods and materials for containment and cleaning up
Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

Handling and storage

Precautions for safe handling
Advice on safe handling : For personal protection see SDS section 8.
Advice on protection against fire and explosion : Avoid formation of aerosol.
Provide sufficient air exchange and/or exhaust in work rooms.
No special protective measures against fire and explosion required.

Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers : Keep containers tightly closed in a cool, well-ventilated place.
Advice on common storage : Keep away from food, drink and animal feedingstuffs.
German storage class : 10
Combustible liquids not in Storage Class 3

Transport information

Land transport (ADR/RID)

UN number:
3082
Shippingopen allclose all
Class:
9
Classification code:
Tunnel-code: (E)Additional labelling: Environmentally Hazardous.
Packaging group:
III
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3082
Proper shipping name and description:
Description of the goods: UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(MIXTURE, CONTAINS ZINC DIALKYL DITHIOPHOSPHATE)
Chemical name:
MIXTURE, CONTAINS ZINC DIALKYL DITHIOPHOSPHATE
Language:
English
Class:
9
Classification code:
Tunnel-code: (E)Additional labelling: Environmentally Hazardous.
Packaging group:
III
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3082
Proper shipping name and description:
Description of the goods: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(MIXTURE, CONTAINS ZINC DIALKYL DITHIOPHOSPHATE)
Chemical name:
MIXTURE, CONTAINS ZINC DIALKYL DITHIOPHOSPHATE
Class:
9
Packaging group:
III
EmS code:
EmS-1 (EmS-2): F-A (S-F)
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3082
Proper shipping name and description:
UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(MIXTURE, CONTAINS ZINC DIALKYL DITHIOPHOSPHATE)
Class:
9
Packaging group:
III
Remarksopen allclose all

Additional transport information

Additional transport information
Environmentally hazardous substance. Marine pollutants. Irritating to the eyes. Keep dry. Keep separated from foodstuffs.

Exposure controls / personal protection

Control parameters
Components CAS-No. Value Control parameters Update Basis
Silicon dioxide 7631-86-9 AGW 4 mg/m3 02 2009 TRGS 900

Personal protective equipment
Respiratory protection : No personal respiratory protective equipment normally required.
Hand protection : Wear suitable protective gloves (e.g. rubber gloves ).
Avoid skin contact with the wetted surfaces of the protective gloves.
In the event of contamination, change protective gloves immediately.
Eye protection : Safety glasses
Skin and body protection : Protective suit
Hygiene measures : Take off all contaminated clothing immediately.
When using, do not eat, drink or smoke.
Wash hands before breaks and immediately after handling the product.
Keep working clothes separately.
Protective measures : Avoid contact with the skin and the eyes.
Do not breathe vapours, aerosols.
When handling observe the usual precautionary measures for chemicals.

Environmental exposure controls
General advice : Do not flush into surface water or sanitary sewer system.
Avoid subsoil penetration.

Stability and reactivity

Reactivity : No hazards to be specially mentioned.
Chemical stability : Stable under normal conditions.
Hazardous reactions : Spontaneous decomposition may start at 150 °C.
After prolonged heating, slow decomposition may start at above 80 °C.
Conditions to avoid : Direct sources of heat.
Materials to avoid : Acids and bases
Hazardous decomposition products : Formation of alkylmercaptans, dialkylsulphides, traces of hydrogen sulphide possible.

Disposal considerations

Product : The relevant EC Directives as well as local, regional and national regulations have to be observed.
It is among the tasks of the polluter to assign the waste to waste codes specific to industrial sectors and processes according to the European Waste Catalogue.
It is recommended that details be sorted out with the waste disposer responsible.

Method of disposal : If utilisation or recycling of the product is not possible, it should be disposed of according to the local regulations and laws, e.g. by incine ration in a suitable plant.

Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal.