Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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First-aid measures

INHALATION: If you feel unwell, remove to fresh air immediately. Get medical attention if cough or other symptoms develop.

EYE CONTACT: Immediately flush eyes with plenty of water for several minutes. Part eyelids with fingers to assure complete flushing. Check for and remove contact lenses if easily possible. Get medical attention if irritation persists.

SKIN CONTACT: Immediately remove contaminated clothing and shoes. Flush skin with large amounts of water, clean off with soap and water. Get medical attention if symptoms develop.

INGESTION: Do NOT induce vomiting. Rinse mouth with water. Never give anything by mouth to an unconscious person. Keep the affected person warm and at rest. Get medical attention immediately.

MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED: Causes serious eye irritation.

SPECIAL PROTECTIVE ACTIONS FOR FIRST-AIDERS: Wear appropriate personal protective equipment such as respirator, goggles, protective gloves, etc.

NOTE TO PHYSICIAN : Treat symptomatically.

Fire-fighting measures

EXTINGUISHING MEDIA: water jet, water fog, foam, dry chemical, CO2, dry sand.
Initial fire: dry chemical, CO2, dry sand.
Large fire: water or foam.

UNSUITABLE EXTINGUISHING MEDIA: Not specified.

SPECIAL HAZARDS: Emits toxic fumes under fire conditions.

FIRE FIGHTING INSTRUCTIONS: Keep unnecessary and unprotected personnel away. Shut off supply if possible. Remove containers to safe place if possible. Keep surrounding areas cool by spraying water. Fight fire from an upwind position.

FIRE FIGHTING EQUIPMENT: Respiratory and eye protection required for fire-fighting personnel. Full protective equipment and self-contained breathing apparatus (SCBA) should be used for all indoor fires and any significant outdoor fires.

HAZARDOUS COMBUSTION PRODUCTS: Carbon oxides, nitrogen oxides.

Accidental release measures

PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
Keep unnecessary and unprotected personnel away. Wear appropriate personal protective equipment as specified in Section 8. Keep upwind, evacuate downwind.

ENVIRONMENTAL PRECAUTIONS: Do not flush into sewer, river or any body of water.

CONTAINMENT/CLEAN-UP METHODS: Absorb or cover with dry earth, sand or other non-combustible material and transfer to sealable containers. Large spills: Dike far ahead of liquid spill for later disposal. Stop leak if possible without personal risk. Avoid runoff to sewers or waterways.

Handling and storage

HANDLING
Technical Measures:
Use only in well-ventilated area. Keep away from heat, sparks, and flame. Use explosion-proof electrical equipment and take precautions against build-up of
electrostatic charges as necessary. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Wear appropriate personal protective equipment. Provide hand and eye wash station near work area. Wash thoroughly after handling.

Ventilation: Use only under local exhaust or general ventilation.

Safe Handling Advice: Do not handle until all safety precautions have been read and understood. Prevent leak and spill. Avoid vapor formation. Do not fall, drop, shock or drag the container. Avoid contact with eye, skin or clothing. Avoid inhalation and ingestion. Use only in well-ventilated area or outdoors.

STORAGE
Storage Conditions:
Protect from direct sunlight. Store in dark and well-ventilated area. Keep away from heat, flame, and all sources of ignition. Keep container tightly closed. Keep
away from strong oxidizers, etc. Store in a segregated and approved area.

Packaging Material: Iron drum or metal can.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

1. Technical protection measures: ENGINEERING CONTROLS - Provide general ventilation. Use closed system or local exhaust ventilation. Provide safety shower and eye wash station near work area.

2. Organisational protection measures: not applicable

3. Hand protection: Protective gloves.

4. Feet protection: Safety boots

5. Body protection: Safety helmet, protective clothing, apron.

6. Eye protection: Safety glasses, goggles, face shield.

7. Respiratory protection: Chemical cartridge respirator with organic vapor cartridge.


EXPOSURE LIMITS :
ACGIH-TLV: Not established.
OSHA-PEL : Not established.

Stability and reactivity

STABILITY: Stable for normal storage and handling.

HAZARDOUS REACTIONS : Reacts with strong oxidizers.

CONDITIONS TO AVOID : Heat.

MATERIALS TO AVOID : Strong oxidizers, etc.

HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon oxides, nitrogen oxides.

Disposal considerations

WASTE FROM RESIDUES: Whatever cannot be saved for recovery may be burned in an approved incinerator or disposed in approved waste facility.
Ensure compliance with local, state, federal and national regulations.

CONTAMINATED PACKAGING: Empty the container completely before disposal.